7,9-Dimethyl-5-phenylsulfonyl-5H-benzo[b]carbazole
نویسندگان
چکیده
In the title compound, C(24)H(19)NO(2)S, the mean plane of the benzo[b]carbazole ring system makes a dihedral angle of 79.26 (5)° with the phenyl ring. The S atom is in a distorted tetra-hedral configuration. The crystal structure exhibits weak C-H⋯O and C-H⋯π inter-actions.
منابع مشابه
9-Methoxy-5-phenylsulfonyl-5H-benzo[b]carbazole
In the title compound, C(23)H(17)NO(3)S, the mean plane of the benzo[b]carbazole ring system makes a dihedral angle of 77.17 (4)° with the phenyl ring. The S atom is in a distorted tetra-hedral configuration. There are three intra-molecular C-H⋯O inter-actions forming five- and six-membered rings with graph-set motifs S(5) and S(6), respectively.
متن کامل8,9-Dimethoxy-5-phenylsulfonyl-5H-benzo[b]carbazole
In the title compound, C(24)H(19)NO(4)S, the benzocarbazole ring system is planar (r.m.s. deviation = 0.016 Å) and forms a dihedral angle of 78.54 (4)° with the sulfonyl-bound phenyl ring. Intra-molecular C-H⋯O inter-actions are observed. A C(8) chain running along the b axis is formed via inter-molecular C-H⋯O hydrogen bonds. The chains are linked via weak C-H⋯ π inter-actions.
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The three title compounds, C26H19NO3S, (1), C27H20N2O8S, (2), and C30H19NO3S, (3), are carbazole derivatives, where (1) and (3) are heterocycle-containing carbazoles with a benzo-furan moiety fused to a carbazole unit. In (2), a di-meth-oxy-nitro-phenyl ring is attached to the carbazole moiety. In the three derivatives, a phenyl-sulfonyl group is attached to the N atom of the carbazole unit. Co...
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The title compounds, C30H18N2O5S, (I), and C27H18N2O4S2, (II), are carbazole derivatives with a phenyl-sulfonyl group and a nitro-phenyl group attached to the carbazole moiety in identical positions in both mol-ecules. A benzo-furan ring system in (I) and a methyl-thio-phene ring in (II) are fused with the respective carbazole moieties on the same sides. The mean plane of the carbazole ring sys...
متن کاملTandem Synthesis and Optical Rotatory Dispersion Studies of a Novel Spiro Lactone (methyl 3-(benzo[d]thiazol-2-ylamino)-7,9-dimethyl-2,6,8,10-tetraoxo-1-oxa-7,9-diazaspiro[4.5]dec-3-ene-4-carboxylate)
Spiro compounds are of interest due to their interesting conformational features and their structural implications on biological systems. The asymmetric characteristic of the molecule due to the chiral spiro carbon is one of the important criteria of the biological activities. These structures are a widespread structural motif found as key elements of numerous drugs and designed medicinal agent...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008